Title: Enhancing Structural Performance of Upcycled Fiber-Reinforced Thermoplastic Composites Through Additively Manufactured Continuous Fiber Reinforced Preforms
Authors: Garam Kim, Eduardo Barocio, Sungjun Choi, Martin Eichenhofer, Jordan Kalman, R. Byron Pipes
DOI: 10.33599/nasampe/c.23.0063
Abstract: The rapid growth in the adoption of lightweight composite materials is also creating a growing demand for recycling methods that could retain some of the structural characteristics of composites. Thermoplastic composites are preferred over thermoset composites when it comes to recycling. Mechanical recycling, which involves shredding composite parts at the end-of-life (EOL) and reforming it into different parts, is a widely discussed recycling process for thermoplastic composites. However, this process involves significant attrition of fibers which results in a reduction in the mechanical and transport properties that depend on the fiber length. Consequently, this method of recycling composites significantly devalues the structural characteristics of the composite. In an effort to enhance the structural characteristics of recycled composites, this paper demonstrates a process that incorporates additively manufactured continuous fiber preforms in a geometry that is compression molded with recycled composite. The continuous fiber preform is designed to serve as the primary structural reinforcement whereas the recycled material serves as a secondary reinforcement in the composite part. This upcycling approach was demonstrated for an aircraft overhead pin bracket geometry. Continuous fiber preforms were manufactured with 60% by volume of carbon fiber-reinforced Poly Ether Ketone Ketone (PEKK) using the 9T Labs continuous fiber Red Series® Build Module. The preforms were designed using Additive Fusion Technology (AFT) to account for reshaping during the molding process and ensure the continuous fiber is located where required. Two types of recycled composite material were used to make the pin bracket: shredded carbon fiber PEKK laminate and shredded EOL additively manufactured carbon fiber reinforced PEKK. The performance of the pin bracket was evaluated by the load at the onset of failure and the ultimate load under tensile loading of the bracket. The results demonstrated the potential of this upcycling method to enhance the structural characteristics of recycled composite materials and compensate for the loss of structural characteristics associated with fiber attrition.
References: 1. Lucintel, Composites Market: Trends, Opportunities and Competitive Analysis 2023-2028, 2023. 2. J. Sloan, The outlook for carbon fiber supply and demand, CompositesWorld, 2021. 3. S. Das, Life cycle assessment of carbon fiber-reinforced polymer composites, International Journal of Life Cycle Assessment, vol. 16, no. 3, pp. 268–282, 2011, doi: 10.1007/s11367-011-0264-z. 4. A. Akbar and K. M. Liew, Assessing recycling potential of carbon fiber reinforced plastic waste in production of eco-efficient cement-based materials, Journal of Cleaner Production, vol. 274, p. 123001, 2020, doi: 10.1016/j.jclepro.2020.123001. 5. D. R. Vieira, R. K. Vieira, and M. Chang Chain, Strategy and management for the recycling of carbon fiber-reinforced polymers (CFRPs) in the aircraft industry: a critical review, International Journal of Sustainable Development & World Ecology, vol. 24, no. 3, pp. 214–223, 2017, doi: 10.1080/13504509.2016.1204371. 6. R. Cherrington et al., Producer responsibility: Defining the incentive for recycling composite wind turbine blades in Europe, Energy Policy, vol. 47, no. 2012, pp. 13–21, 2012, doi: 10.1016/j.enpol.2012.03.076. 7. T. Chen, C. D. Mansfield, L. Ju, and D. G. Baird, The influence of mechanical recycling on the properties of thermotropic liquid crystalline polymer and long glass fiber reinforced polypropylene, Composites Part B: Engineering, vol. 200, no. August, p. 108316, 2020, doi: 10.1016/j.compositesb.2020.108316. 8. A. E. Krauklis, C. W. Karl, A. I. Gagani, and J. K. Jørgensen, Composite material recycling technology—state-of-the-art and sustainable development for the 2020s, Journal of Composites Science, vol. 5, no. 1, p. 28, 2021. 9. H. Li and K. Englund, “Recycling of carbon fiber-reinforced thermoplastic composite wastes from the aerospace industry,” Journal of Composite Materials, vol. 51, no. 9, pp. 1265–1273, 2017, doi: 10.1177/0021998316671796. 10. A. Rahimizadeh, J. Kalman, K. Fayazbakhsh, and L. Lessard, Recycling of fiberglass wind turbine blades into reinforced filaments for use in Additive Manufacturing, Composites Part B: Engineering, vol. 175, no. July, p. 107101, 2019, doi: 10.1016/j.compositesb.2019.107101. 11. C. Xiong, Q. Li, T. Lan, H. Li, W. Long, and F. Xing, Sustainable use of recycled carbon fiber reinforced polymer and crumb rubber in concrete: mechanical properties and ecological evaluation, Journal of Cleaner Production, vol. 279, p. 123624, 2021, doi: 10.1016/j.jclepro.2020.123624. 12. S. R. Naqvi, H. M. Prabhakara, E. A. Bramer, W. Dierkes, R. Akkerman, and G. Brem, A critical review on recycling of end-of-life carbon fibre/glass fibre reinforced composites waste using pyrolysis towards a circular economy, Resources, Conservation and Recycling, vol. 136, no. April, pp. 118–129, 2018, doi: 10.1016/j.resconrec.2018.04.013. 13. M. Xing, Z. Li, G. Zheng, Y. Du, C. Chen, and Y. Wang, Recycling of carbon fiber-reinforced epoxy resin composite via a novel acetic acid swelling technology, Composites Part B: Engineering, vol. 224, no. June, p. 109230, 2021, doi: 10.1016/j.compositesb.2021.109230. 14. H. Lee, I. Ohsawa, and J. Takahashi, Effect of plasma surface treatment of recycled carbon fiber on carbon fiber-reinforced plastics (CFRP) interfacial properties, Applied Surface Science, vol. 328, pp. 241–246, 2015, doi: 10.1016/j.apsusc.2014.12.012. 15. X. Xue, S.-Y. Liu, Z.-Y. Zhang, Q.-Z. Wang, and C.-Z. Xiao, A technology review of recycling methods for fiber-reinforced thermosets, Journal of Reinforced Plastics and Composites, p. 07316844211055208, 2021. 16. E. Barocio, M. Eichenhofer, J. Kalman, F. Fjeld, J. Kirchoff, G. Kim, B. Pipes, Compression Molding of Hybrid Continuous and Discontinuous Fiber Reinforced Thermoplastics for Enhancing Strength Characteristics. in SAMPE Conference Proceedings, 2023, pp. 1730–1743.
Conference: CAMX 2023
Publication Date: 2023/10/30
SKU: TP23-0000000063
Pages: 17
Price: $34.00
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