Title: Crystallinity Variability in Thick Section PET Composites
Authors: Jacob A. Reinholz, Luke R. Gibbon, Eric S. Hall, Robert J. Hart, Chad A. Ulven
DOI: 10.33599/nasampe/c.23.0213
Abstract: Thermoplastic polymer crystallinity is partially dependent on processing parameters during the molding process. Crystallinity can be altered by temperature, pressure, and heat transfer rates during the processing of thermoplastic composites. Compression molding is a popular technique for rapid manufacturing of thermoplastic and glass fiber reinforced composites. During the compression molding of the thick sectioned polyethylene terephthalate (PET) composites, crystallinity and resulting properties can be altered not only globally but also through thickness. Given the low thermal conductivity of composites utilizing PET and glass fibers, the heat cycle from the surface to the interior of the panel are significantly different thereby directly affecting the mechanical properties of the PET and subsequent composite. This study isolates different processing parameters on thin section panels and expands that understanding to thick section layer wise study of crystallinity. Understanding the variation of mechanical properties through thickness allows for the optimization of properties and more accurate finite element modeling of structures designed with these types of composites in mind. Mechanical characterization included tensile, flexural, interlaminar shear, and compression properties. Crystallinity was characterized utilizing Differential Scanning Calorimetry (DSC) and all specimens were post processed with a waterjet eliminating the heat affected zone of traditional specimen preparation techniques.
References: [1] Y. Ma, Y. Yang, T. Sugahara, and H. Hamada, “A study on the failure behavior and mechanical properties of unidirectional fiber reinforced thermosetting and thermoplastic composites,” Composites Part B: Engineering, vol. 99, pp. 162–172, 2016, doi: 10.1016/j.compositesb.2016.06.005.
[2] “$9.3 Billion Automotive Composites (Glass, Carbon, Natural) Market - Global Forecast to 2025,” Business Wire, Jan. 22, 2021.
[3] J. Moothoo, M. Bar, and P. Ouagne, “Mechanical properties of compression moulded aggregate-reinforced thermoplastic composite scrap,” Journal of Composites Science, vol. 5, no. 11, Nov. 2021, doi: 10.3390/jcs5110299.
[4] I. M. Daniel and O. Ishai, Engineering Mechanics of Composite Materials, 2nd ed. New York: Oxford University Press, 2006.
[5] H. Ning, N. Lu, A. A. Hassen, K. Chawla, M. Selim, and S. Pillay, “A review of Long fibre thermoplastic (LFT) composites,” International Materials Reviews, vol. 65, no. 3, pp. 164–188, Apr. 2020, doi: 10.1080/09506608.2019.1585004.
[6] S. A. Mirdehghan, “Fibrous polymeric composites,” Engineered Polymeric Fibrous Materials, pp. 1–58, Jan. 2021, doi: 10.1016/B978-0-12-824381-7.00012-3.
[7] M. Etcheverry and S. E. Barbosa, “Glass fiber reinforced polypropylene mechanical properties enhancement by adhesion improvement,” Materials, vol. 5, no. 6, pp. 1084–1113, 2012, doi: 10.3390/ma5061084.
[8] C. H. Zweben, “Composites: Overview,” Encyclopedia of Condensed Matter Physics, pp. 192–208, Jan. 2005, doi: 10.1016/B0-12-369401-9/00545-3.
[9] R. F. Boyer, “Glassy transitions in semi-crystalline polymers,” Journal Polymer Science, 1975.
[10] N. A. Barber, Polyethylene Terephthalate: Uses, Properties, and Degradation. Nova Science Publishers, Inc, 2017.
[11] B. Demirel, A. Yaraş, and H. ELÇİÇEK, “Crystallization Behavior of PET Materials,” Balıkesir Üniversitesi Fen Bilimleri Enstitü Dergisi, vol. 13, pp. 26–35, Jan. 2011.
[12] P.-Y. B. Jar, R. Mulone, P. Davies, and H.-H. Kausch, “A study of the effect of forming temperature on the mechanical behaviour of carbon-fibre/peek composites,” Composites Science and Technology, vol. 46, no. 1, pp. 7–19, 1993, doi: 10.1016/0266-3538(93)90076-S.
[13] L. Ye, K. Friedrich, J. Kästel, and Y.-W. Mai, “Consolidation of unidirectional CF/PEEK composites from commingled yarn prepreg,” Composites Science and Technology, vol. 54, no. 4, pp. 349–358, 1995, doi: 10.1016/0266-3538(95)00061-5.
[14] J. Bernhardsson and R. Shishoo, “Effect of processing parameters on consolidation quality of GF/PP commingled yarn based composites,” Journal of Thermoplastic Composite Materials, vol. 13, no. 4, pp. 292–313, 2000, doi: 10.1106/X5VY-2TF0-Y3UA-D5DQ.
[15] R. H. Elleithy, M. E. Ali Mohsin, I. Ali, and S. M. Al-Zahrani, “Effect of nano - SiO
Conference: CAMX 2023
Publication Date: 2023/10/30
SKU: TP23-0000000213
Pages: 13
Price: $26.00
Get This Paper