DIGITAL LIBRARY: CAMX 2025 | ORLANDO, FL | SEPTEMBER 8-11

Get This Paper

3D Printed Continuous Basalt-Fibre/PA12 Composites Under Space Environment: A Morphological and Chemical Assessment

Description

Title: 3D Printed Continuous Basalt-Fibre/PA12 Composites Under Space Environment: A Morphological and Chemical Assessment

Authors: PL Pichard, B. Delacourt, U Lafont and A Le Duigou

DOI: 10.33599/nasampe/c.25.66

Abstract: Establishing permanent infrastructures on the Moon will require extensive use of autonomous additive manufacturing processes. In an in-situ resource utilization perspective (ISRU), lunar regolith has already been processed into fibres which can further be embedded into a polymer matrix. Such a composite material, made of polyamide 12 reinforced by continuous basalt fibres (referred to as PA12-basalt) is here manufactured via continuous filament fabrication (CFF). The 3D-printed parts are then exposed to three accelerated ageing and space conditions: hygrothermal ageing, ultra-violet (UV) irradiation and thermal cycling in vacuum (TVAC). The temperature conditions of the tests, most of which exceeding the glass transition temperature of PA12, act as an annealing process on the parts. Simultaneously, significant changes at the polymer chain level when exposed to hygrothermal ageing or UV light, however without drastically influencing the optical properties nor the surface morphology (with the noticeable exception of the erosion reported for samples exposed to atomic oxygen). Overall, under the tested conditions, PA12-basalt appears as a suitable candidate material for 3D-printed structures both in low-Earth orbit and on the Moon.

References: [2] [3] [4] [5] [6] [7] [8] [9] [10] [11] [12] [13] [14] [15] [16] [17] [18] [19] [20] [21] [22] [23] [24] [25] [26] [27] [28] [29] [30] [31] [32] [33] [34] [35] [36] [37] [38] [39] [40] [41] [42] [43] M. Ortega Varela De Seijas et al., “Closing the loop in space 3D prin ng: Effect of vacuum, recycling, and UV aging on high performance thermoplas cs produced via filament extrusion addi ve manufacturing,” Acta Astronau ca, p. S0094576524001322, Mar. 2024, doi: 10.1016/j.actaastro.2024.03.015. D. Sher, “China operates con nuous composites 3D printer in space,” VoxelMa ers. Accessed: Apr. 28, 2025. [Online]. Available: h ps://www.voxelma ers.com/china-operates-autonomous-con nuous-composites-3d-printer-in-space/ A. Sgamba et al., “URBAN: Conceiving a lunar base using 3D prin ng technologies,” in Proceedings of the 69th Interna onal Astronau cal Congress (IAC), Bremen, Oct. 2018. H. Li et al., “3D Prin ng and Solvent Dissolu on Recycling of Polylac de–Lunar Regolith Composites by Material Extrusion Approach,” Polymers, vol. 12, no. 8, p. 1724, Jul. 2020, doi: 10.3390/polym12081724. M. Azami, P.-L. Aubin Fournier, and K. Skonieczny, “Addi ve Manufacturing of Polyether Ether Ketone (PEEK)/Lunar Regolith Composites via Fused Filament Fabrica on,” Earth and Space 2024, Oct. 10, 2024. [Online]. Available: h ps://doi.org/10.1061/9780784485736.086 P. Pichard et al., “Regolith-based composite manufacturing by fused deposi on modelling (FDM),” presented at the Space Resources Week, Luxembourg, 2022. T. Becker, A. Lüking, T. Meinert, S. Panajotovic, and J. C. A. Romero, “MoonFibre -Fibres from Lunar Regolith,” 2019, doi: 10.13140/RG.2.2.12287.36007. K. W. Farries, P. Visin n, S. T. Smith, and P. Van Eyk, “Sintered or melted regolith for lunar construc on: state-of-the-art review and future research direc ons,” Construc on and Building Materials, vol. 296, p. 123627, Aug. 2021, doi: 10.1016/j.conbuildmat.2021.123627. V. S. Engelschiøn et al., “EAC-1A: A novel large-volume lunar regolith simulant,” Sci Rep, vol. 10, no. 1, p. 5473, Mar. 2020, doi: 10.1038/s41598-02062312-4. I. Cheibas, M. Arnhof, and B. Rich, “Basalt fiber composites for the robo c fabrica on of a lunar habitat,” p. 11 p., 2022, doi: 10.3929/ETHZ-B000603678. B. Rich, “ADVANCED CONCEPTS FOR ISRU-BASED ADDITIVE MANUFACTURING OF PLANETARY HABITATS”. C. Houriet et al., “3D Prin ng of Liquid Crystal Polymers for Space Applica ons,” Adv Materials Technologies, p. 2400571, Oct. 2024, doi: 10.1002/admt.202400571. M. Adams, “The Degrada on of Polymeric Spacecra Materials by Far-UV Radia on and Atomic Oxygen,” University of Connec cut, USA, 1993. S. Tompkins, “EFFECTS OF THERMAL CYCLING ON COMPOSITE MATERIALS FOR SPACE STRUCTURES”. M. Parker et al., “3D prin ng of con nuous carbon fiber reinforced polyphenylene sulfide: Exploring printability and importance of fiber volume frac on,” Addi ve Manufacturing, vol. 54, p. 102763, Jun. 2022, doi: 10.1016/j.addma.2022.102763. A. Le Duigou et al., “Thermomechanical performance of con nuous carbon fibre composite materials produced by a modified 3D printer,” Heliyon, vol. 9, no. 3, p. e13581, Mar. 2023, doi: 10.1016/j.heliyon.2023.e13581. M. D. Brown, “Moisture Absorp on and Desorp on Effects on Mechanical Behavior in Specialty Polyamide Products,” 2019, Accessed: May 25, 2023. [Online]. Available: h ps://www.proquest.com/disserta ons-theses/moisture-absorp on-desorp on-effects-on/docview/2384874218/se-2 Standard Prac ce for Condi oning Plas cs for Tes ng, ASTM D618-21, 2021. Adhesive bonding for spacecra and launcher applica ons, ECSS-Q-ST-70-16C, Noordwijk, Netherlands., 2008. Thermal tes ng for the evalua on of space materials, processes, mechanical parts and assemblies, ECSS-Q-ST-70-04C, Noordwijk, Netherlands., 2008. S. Gogolewski, K. Czerntawska, and M. Gastorek, “Effect of annealing on thermal proper es and crystalline structure of polyamides. Nylon 12 (polylaurolactam),” Colloid Polymer Sci, vol. 258, no. 10, pp. 1130–1136, Oct. 1980, doi: 10.1007/BF01382456. J.-P. Williams, D. A. Paige, B. T. Greenhagen, and E. Se on-Nash, “The global surface temperatures of the Moon as measured by the Diviner Lunar Radiometer Experiment,” Icarus, vol. 283, pp. 300–325, Feb. 2017, doi: 10.1016/j.icarus.2016.08.012. T. Shimokawa et al., “Effect of Thermal Cycling on Microcracking and Strength Degrada on of High-Temperature Polymer Composite Materials for Use in Next-Genera on SST Structures,” Journal of Composite Materials, vol. 36, no. 7, pp. 885–895, Apr. 2002, doi: 10.1177/0021998302036007469. M. Lafariefrenot, “Damage mechanisms induced by cyclic ply-stresses in carbon–epoxy laminates: Environmental effects,” Interna onal Journal of Fa gue, vol. 28, no. 10, pp. 1202–1216, Oct. 2006, doi: 10.1016/j.ijfa gue.2006.02.014. L. Sang, C. Wang, Y. Wang, and Z. Wei, “Thermo-oxida ve ageing effect on mechanical proper es and morphology of short fibre reinforced polyamide composites – comparison of carbon and glass fibres,” RSC Adv., vol. 7, no. 69, pp. 43334–43344, 2017, doi: 10.1039/C7RA07884F. U. LAFONT, M. MUNCK, J. WESSING, M. TEROL-SANCHEZ, and R. RAMPINI, “3D prin ng of mul func onal polymer for space applica on,” p. 13 pages, 2022, doi: 10.13009/EUCASS2022-7453. A. Hurtado Macias et al., “Compara ve study between UVB 313 nm, UVC 254 nm, and far UVC 222 nm light on the aging of polyamide 66,” Heliyon, vol. 10, no. 20, p. e39415, Oct. 2024, doi: 10.1016/j.heliyon.2024.e39415. O. O. Diogo, “Thermo-oxyda on des polyamides”. T. Pu onen, M. Salmi, and J. Partanen, “Mechanical proper es and fracture characteriza on of addi ve manufacturing polyamide 12 a er accelerated weathering,” Polymer Tes ng, vol. 104, p. 107376, Dec. 2021, doi: 10.1016/j.polymertes ng.2021.107376. X.-F. Wei et al., “Ageing proper es and polymer/fuel interac ons of polyamide 12 exposed to (bio)diesel at high temperature,” npj Mater Degrad, vol. 3, no. 1, p. 1, Jan. 2019, doi: 10.1038/s41529-018-0065-y. W. Dong and P. Gijsman, “Influence of temperature on the thermo-oxida ve degrada on of polyamide 6 films,” Polymer Degrada on and Stability, vol. 95, no. 6, pp. 1054–1062, Jun. 2010, doi: 10.1016/j.polymdegradstab.2010.02.030. M. Handwerker, J. Wellnitz, H. Marzbani, and U. Tetzlaff, “Annealing of chopped and con nuous fibre reinforced polyamide 6 produced by fused f ilament fabrica on,” Composites Part B: Engineering, vol. 223, p. 109119, Oct. 2021, doi: 10.1016/j.compositesb.2021.109119. G. Simha Martynková et al., “Polyamide 12 Materials Study of Morpho-Structural Changes during Laser Sintering of 3D Prin ng,” Polymers, vol. 13, no. 5, p. 810, Mar. 2021, doi: 10.3390/polym13050810. H. Gao et al., “Comparisons between basalt for con nuous fiber and ordinary basalt,” Ceramics Interna onal, vol. 51, no. 1, pp. 132–146, Jan. 2025, doi: 10.1016/j.ceramint.2024.10.383. L.-T. Lim, I. J. Bri , and M. A. Tung, “Sorp on and transport of water vapor in nylon 6,6 film,” J. Appl. Polym. Sci., vol. 71, no. 2, pp. 197–206, Jan. 1999, doi: 10.1002/(SICI)1097-4628(19990110)71:2<197::AID-APP2>3.0.CO;2-J. I. Ksouri, O. De Almeida, and N. Haddar, “Long term ageing of polyamide 6 and polyamide 6 reinforced with 30% of glass fibers: physicochemical, mechanical and morphological characteriza on,” J Polym Res, vol. 24, no. 8, p. 133, Aug. 2017, doi: 10.1007/s10965-017-1292-6. C. Arslan and M. Dogan, “The effects of silane coupling agents on the mechanical proper es of basalt fiber reinforced poly(butylene terephthalate) composites,” Composites Part B: Engineering, vol. 146, pp. 145–154, Aug. 2018, doi: 10.1016/j.compositesb.2018.04.023. A. Issa and A. Luyt, “Kine cs of Alkoxysilanes and Organoalkoxysilanes Polymeriza on: A Review,” Polymers, vol. 11, no. 3, p. 537, Mar. 2019, doi: 10.3390/polym11030537. T. Dooher, E. Archer, T. Walls, A. McIlhagger, and D. Dixon, “Ageing of laser sintered glass-filled Polyamide 12 (PA12) parts at elevated temperature and humidity,” Polymers and Polymer Composites, vol. 29, no. 9_suppl, pp. S1294–S1304, Nov. 2021, doi: 10.1177/09673911211027127. A. R. Bunsell, Handbook of Proper es of Tex le and Technical Fibres. Elsevier, 2018. B. Hassanpour and V. M. Karbhari, “Characteris cs and Models of Moisture Uptake in Fiber-Reinforced Composites: A Topical Review,” Polymers, vol. 16, no. 16, p. 2265, Aug. 2024, doi: 10.3390/polym16162265. A. S. Nielsen and R. Pyrz, “A Raman study into the effect of transcrystallisa on on thermal stresses in embedded single fibres”. P. P. Parlevliet, H. E. N. Bersee, and A. Beukers, “Residual stresses in thermoplas c composites—A study of the literature—Part I: Forma on of residual stresses,” Composites Part A: Applied Science and Manufacturing, vol. 37, no. 11, pp. 1847–1857, Nov. 2006, doi: 10.1016/j.compositesa.2005.12.025. 16 [44] A. Roger, D. Sallet, and J. Lemaire, “Photochemistry of alipha c polyamides. 3. Mechanisms of photooxida on of polyamides 6, 11, and 12 at short wavelength,” Macromolecules, vol. 18, no. 9, pp. 1771–1775, Sep. 1985, doi: 10.1021/ma00151a021. [45] [46] [47] [48] [49] [50] [51] [52] S. Zhang et al., “Surface Roughening of Irradia on-Ac vated Basalt Fiber through In Situ Growth of SiO2: Effects on Crystalliza on and Proper es of PP Composites,” Materials, vol. 16, no. 16, p. 5657, Aug. 2023, doi: 10.3390/ma16165657. D. Dixon and A. Boyd, “Degrada on and accelerated ageing of poly(ether block amide) thermoplas c elastomers,” Polymer Engineering & Sci, vol. 51, no. 11, pp. 2203–2209, Nov. 2011, doi: 10.1002/pen.21992. B. Sanders, E. Cant, H. Amel, and M. Jenkins, “The Effect of Physical Aging and Degrada on on the Re-Use of Polyamide 12 in Powder Bed Fusion,” Polymers, vol. 14, no. 13, p. 2682, Jun. 2022, doi: 10.3390/polym14132682. S. V. Levchik, E. D. Weil, and M. Lewin, “Thermal decomposi on of alipha c nylons,” Polym. Int., vol. 48, no. 7, pp. 532–557, Jul. 1999, doi: 10.1002/(SICI)1097-0126(199907)48:7<532::AID-PI214>3.0.CO;2-R. S. Maïza et al., “Physicochemical and mechanical degrada on of polyamide 11 induced by hydrolysis and thermal aging,” J of Applied Polymer Sci, vol. 136, no. 23, p. 47628, Jun. 2019, doi: 10.1002/app.47628. C. Ghimouz, J. P. Kenné, and L. A. Hof, “Environmental aging influence on mechanical proper es of addi ve manufactured polyamide parts: A sta s cal approach,” J of Applied Polymer Sci, vol. 141, no. 42, p. e56091, Nov. 2024, doi: 10.1002/app.56091. X. Liu et al., “Enhancing the mechanical strength of Mul Jet Fusion–printed polyamide 12 and its glass fiber-reinforced composite via hightemperature annealing,” Addi ve Manufacturing, vol. 46, p. 102205, Oct. 2021, doi: 10.1016/j.addma.2021.102205. I. Ferreira, C. Melo, R. Neto, M. Machado, J. L. Alves, and S. Mould, “Study of the annealing influence on the mechanical performance of PA12 and PA12 f ibre reinforced FFF printed specimens,” RPJ, vol. 26, no. 10, pp. 1761–1770, Oct. 2020, doi: 10.1108/RPJ-10-2019-0278.

Conference: CAMX 2025

Publication Date: 2025/09/08

SKU: 66

Pages: 17

Price: $34.00

Get This Paper