Title: High Throughput Carbon Fiber Surface Modification
Authors: Zachary R. Hinton, Munetaka Kubota, Lavénia Thursch, Joseph Deitzel, Giuseppe R. Palmese, and Nicolas J. Alvarez
DOI: 10.33599/nasampe/s.19.1528
Abstract: Typical commercial surface treatments for continuous carbon fibers are often unavailable for short fibers. As such, there is little variety of chopped fiber surfaces leading to non-ideal coating solutions which result in poor interfacial compatibility between fibers and matrix. In this work we develop a method of applying a highly effective coating using a high throughput technique for chopped carbon fibers. We show the ability to tune both the coating thickness and chemical functionality using processing parameters. The coatings are evaluated using EDS and X-ray photoelectron spectroscopy (XPS) for uniformity and composition. Using this technique, thermoplastic composites are highlighted showing an increase in interfacial shear strength (IFSS) of 25 MPa. This process shows promise for increasing the throughput of surface treatment of chopped fiber on the industrial scale. With this technique, we hope to increase the overall performance of commercial, discontinuous composites as well as expand the possibilities of carbon fiber technologies.
References: 1. Biron, Michel. Thermoplastics and Thermoplastic Composites. Waltham, MA: William Andrew, 2013. 2. Béland, Sylvie. High Performance Thermoplastic Resins and their Composites. Park Ridge, NJ: Noyes Data Corp., 1991. 3. Park, Soo-Jin & Seo, Min-Kang. Interface Science and Composites. Waltham, MA: Academic Press, 2011. 4. Plueddemann, Edwin P. Silane Coupling Agents, 2nd Ed. New York, NY: Springer Science-Business Media, 1991. 5. Jiang, S., Li, Q., Zhao, Y., Wang, J. & Kang, M. “Effect of surface silanization of carbon fiber on mechanical properties of carbon fiber reinforced polyurethane composites.” Composites Science and Technology 110 (2015): 87-94. http://dx.doi.org/10.1016/j.compscitech.2015.01.022 6. Xu, Yunsheng & Chung, D.D.L. “Silane-treated carbon fiber for reinforcing cement.” Carbon 39 (2001): 1995-2001. https://doi.org/10.1016/S0008-6223(01)00028-8 7. Zhang, F., Sauter, K., Larsen, A.M., Findley, D.A., Davis, R.C., Samha, H., & Linford, M.R. “Chemical Vapor Deposition of Three Aminosilanes on Silicon Dioxide: Surface Characterization, Stability, Effects of Silane Concentration, and Cyanine Dye Adsorption.” Langmuir 26 (2010): 14648-14654. https://doi.org/10.1021/la102447y 8. Deitzel, J.M., Kubota, M., Alvarez, N., Palmese, G., Bortner, M., & Riffle, J. “Surface Treatment of TuFF Pitch Carbon Fiber for Adhesion Promotion in High Tg Thermoplastic Composites”. SAMPE Technical Conference Proceedings. Charlotte, NC, May 20-23, 2019. Society for the Advancement of Material and Process Engineering. (in press)
Conference: SAMPE 2019 - Charlotte, NC
Publication Date: 2019/05/20
SKU: TP19--1528
Pages: 9
Price: FREE
Get This Paper