Search

DIGITAL LIBRARY: SAMPE 2020 | VIRTUAL SERIES

Get This Paper

Embodied Energy of Pyrolysis and Solvolysis Processes for Recycling Carbon Fiber Reinforced Polymer Waste

Description

Title: Embodied Energy of Pyrolysis and Solvolysis Processes for Recycling Carbon Fiber Reinforced Polymer Waste

Authors: Komal Kooduvalli, Samantha Ford, Sabrinna Romero, Isaac Sloan, Hayley Coughlin, John Unser, Uday Vaidya and Soydan Ozcan

DOI: 10.33599/nasampe/s.20.0371

Abstract: Composites are being increasingly used in aerospace, automotive, energy, gas storage, marine, infrastructure, sporting goods, and other secondary industries. The key drivers for composites is light weight, high specific strength, and durability. The composites market is projected to grow from $72.58 billion to $115.43 billion by 2022 (CAGR of 8.13% between 2017-2022) with carbon fiber demand alone projected to soar to 150,000 metric tons by 2020 globally, implying that much of this will reach their End-of-Life (EOL) stage in the coming years. Due to rising disposal cost of landfills and lack of space, it is important to diversify composite waste streams in order to address feasible options related to recovery, reuse, and remanufacture. The Institute for Advanced Composites Manufacturing Innovation (IACMI) has partnered with several industry collaborators to address the issue of carbon fiber reinforced polymer (CFRP) waste. This paper highlights the significance, complexities, application, and the embodied energy (EE) associated with two types of recycling processes for EOL CFRP. The cumulative energy demand (CED) method was applied to analyze the pyrolysis and solvolysis processes using the life cycle assessment (LCA) software SimaPro v.9.0.0.33 and the FRPC Energy Use Estimation Tool developed by the Oak Ridge National Laboratory. Data was sourced to model the amount of fiber, resin, and embodied energy that may be recovered from each recycling system considering 1 kg of carbon fiber-epoxy laminate as benchmark. It was found that a continuous natural gas furnace based pyrolysis system consumes a total of 52 MJ/kg by default and 42 MJ/kg while reusing syngas generated within the system as avoided energy. The supercritical solvolysis process considered for analysis presented a total embodied energy of 257 MJ/kg.

References: [1] S. M. C. Alves, F. S. da Silva, M. V. Donadon, R. R. Garcia, and E. J. Corat, "Process and characterization of reclaimed carbon fiber composites by pyrolysis and oxidation, assisted by thermal plasma to avoid pollutants emissions," Journal of Composite Materials, vol. 52, no. 10, pp. 1379-1398, 2018. [2] Y. Khalil, "Comparative environmental and human health evaluations of thermolysis and solvolysis recycling technologies of carbon fiber reinforced polymer waste," Waste Management, vol. 76, pp. 767-778, 2018. [3] S. Pimenta and S. T. Pinho, "Recycling carbon fibre reinforced polymers for structural applications: Technology review and market outlook," Waste management, vol. 31, no. 2, pp. 378-392, 2011. [4] K. Wong, C. Rudd, S. Pickering, and X. Liu, "Composites recycling solutions for the aviation industry," Science China Technological Sciences, vol. 60, no. 9, pp. 1291-1300, 2017. [5] S. Naqvi, H. M. Prabhakara, E. Bramer, W. Dierkes, R. Akkerman, and G. Brem, "A critical review on recycling of end-of-life carbon fibre/glass fibre reinforced composites waste using pyrolysis towards a circular economy," Resources, conservation and recycling, vol. 136, pp. 118-129, 2018. [6] G. Oliveux, L. O. Dandy, and G. A. Leeke, "Current status of recycling of fibre reinforced polymers: Review of technologies, reuse and resulting properties," Progress in Materials Science, vol. 72, pp. 61-99, 2015. [7] C. Morin, A. Loppinet-Serani, F. Cansell, and C. Aymonier, "Near-and supercritical solvolysis of carbon fibre reinforced polymers (CFRPs) for recycling carbon fibers as a valuable resource: State of the art," The journal of supercritical fluids, vol. 66, pp. 232-240, 2012. [8] M. Prinçaud, C. Aymonier, A. Loppinet-Serani, N. Perry, and G. Sonnemann, "Environmental feasibility of the recycling of carbon fibers from CFRPs by solvolysis using supercritical water," ACS Sustainable Chemistry & Engineering, vol. 2, no. 6, pp. 1498-1502, 2014. [9] C. C. Knight, "Recycling high-performance carbon fiber reinforced polymer composites using sub-critical and supercritical water," 2013. [10] "SimaPro," 9.0.0.33 ed: PRé Consultants, 2018. [11] "DATASMART LCI Package," ed: Long Trail Sustainability, 2015. [12] G. Wernet, C. Bauer, B. Steubing, J. Reinhard, E. Moreno-Ruiz, and B. Weidema, "The ecoinvent database version 3 (part I): overview and methodology," The International Journal of Life Cycle Assessment, vol. 21, no. 9, pp. 1218-1230, 2016. [13] S. Das and K. Armstrong. FRPC Energy Use Estimation Tool [Online]. Available: http://energytoolestimator.com/ [14] A. Cunliffe, N. Jones, and P. Williams, "Pyrolysis of composite plastic waste," Environmental technology, vol. 24, no. 5, pp. 653-663, 2003. [15] Monitoring by Control Technique - Wet Scrubber For Particulate Matter. Available: https://www.epa.gov/air-emissions-monitoring-knowledge-base/monitoring-control-technique-wet-scrubber-particulate-matter [16] P. H. Daniel Mussatti, "Air Pollution Control Cost Manual," in "Section 6: Particulate Matter Controls; Chapter 2: Wet Scrubbers for Particulate Matter," U.S. EPAJuly 15, 2002 2002, Available: https://www.epa.gov/air-emissions-monitoring-knowledge-base/monitoring-control-technique-wet-scrubber-particulate-matter, Accessed on: June 20, 2019. [17] White Coffee. (March 12). “Organic Breakfast Blend” Available: http://www.whitecoffee.com/store/organic-breakfast-blend/227fdc28-e64b-4673-a499-f7a7fbad0087?category=single%20serve [18] H. U. Sokoli, "Chemical Solvolysis as an Approach to Recycle Fibre Reinforced Thermoset Polymer Composites and Close the End-of the Life Cycle." [19] A. A. Morini, M. J. Ribeiro, and D. Hotza, "Early-stage materials selection based on embodied energy and carbon footprint," Materials & Design, vol. 178, p. 107861, 2019. [20] "Embodied energy," vol. 2017, ed: Composites UK, 2018. [21] G. Rebitzer et al., "Life cycle assessment: Part 1: Framework, goal and scope definition, inventory analysis, and applications," Environment international, vol. 30, no. 5, pp. 701-720, 2004. [22] M. Duda and J. S. Shaw, "Life cycle assessment," Society, journal article vol. 35, no. 1, pp. 38-43, November 01 1997. [23] D. Gürzenich, J. Mathur, N. K. Bansal, and H.-J. Wagner, "Cumulative energy demand for selected renewable energy technologies," The International Journal of Life Cycle Assessment, vol. 4, no. 3, pp. 143-149, 1999. [24] S. Kara and S. Manmek, "Composites: Calculating their Embodied Energy," The University of New South Wales, 2009. [25] Environmental management-life cycleassessment-principles and framework, 2006. [26] Environmental management-life cycle assessment-requirements and guidelines, 2006. [27] T. Suzuki and J. Takahashi, "Prediction of energy intensity of carbon fiber reinforced plastics for mass-produced passenger cars," in Proceedings of 9th Japan International SAMPE Symposium, 2005, pp. 14-19. [28] F. Meng, J. McKechnie, and S. J. Pickering, "An assessment of financial viability of recycled carbon fibre in automotive applications," Composites Part A: Applied Science and Manufacturing, vol. 109, pp. 207-220, 2018.

Conference: SAMPE 2020 | Virtual Series

Publication Date: 2020/06/01

SKU: TP20-0000000371

Pages: 10

Price: FREE

Get This Paper