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DIGITAL LIBRARY: SAMPE neXus 2021 | JUNE 29 - JULY 1

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Recyclamine® - Novel Amine Building Blocks for a Sustainable World

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Title: Recyclamine® - Novel Amine Building Blocks for a Sustainable World

Authors: Pradip Kumar Dubey, Satish Kumar Mahanth, Amit Dixit

DOI: 10.33599/nasampe/s.21.0632

Abstract: Epoxy thermosets are high performance polymers having superior mechanical, adhesive, and very good chemical resistant properties, preferred for versatile applications in Composites, Coating, Construction, Electrical & Electronics segments. Unfortunately, unlike thermoplastics, thermosetting plastics are not recyclable. Thermoset waste generated during manufacturing and end-of-life pose significant ecological, environmental and societal challenges all over the world. A new class of high-performance amine-based epoxy curing agents, Recyclamines®, have been developed for the creation of inherently recyclable thermoset materials. Recyclamine® technology is based on specifically engineered recyclamine® curing agents which enables cleavage points that converts thermosetting epoxies into thermoplastics under specific set of conditions. These cleavage points are reversible at specific condition and hence enable disintegration of the thermoset matrix. During this disintegration process, all the valuable reinforcing components such as carbon fiber, glass fiber, kevlar®, plastic material in a thermoset composite, can be recovered. More importantly, the thermoset manufacturing waste can be recycled, reused and re-integrated back into the manufacturing ecosystem. In this paper general overview of the recyclable epoxy technology and platform chemistry is presented, including the underlying chemical principle that fosters recycling and recovery of the cured thermoset epoxy. Recyclable epoxy systems based on Recyclamine® are developed and characterized for process and performance properties. Recycling and recovery of epoxy thermoset composite is demonstrated as proof of the concept.

References: 1. Lee,Henry.,Neville,Kris.Handbook of Epoxy Resins; New York: McGraw-Hill, 1967. 2. Debdatta,Ratna.Handbook of Thermoset Resins: Shropshire,UK:iSmithers,2009. 3. Hughes, Kristin., “3 ways we are making an impact on plastic pollution”. World Economic Forum, 2019. 4. Connora Technologies, US Patent 20190016667A1,“Salts of Diaminoacetals and Diaminoketals and Their Synthesis and Their Transformations to Diaminoacetals and Diaminoketals”.2019. 5. Connora Technologies, US Patent 20190016667A,“Synthesis of and compositions containing Diaminoacetals and Diaminoacetals.”2019. 6. ASTM Standard. D2196-05, “Standard Test Methods for Rheological Properties of Non-Newtonian Materials by Rotational (Brookfield type) Viscometer”, ASTM International, West Conshohocken, PA, 2005, www.astm.org. 7. ASTM Standard D2471-99, “Standard Test Method for Gel Time and Peak Exothermic Temperature of Reacting Thermosetting Resins”, ASTM International West Conshohocken, PA, 1999, www.astm.org. 8. ISO Standard 2555:2018, “Plastics — Resins in the liquid state or as emulsions or dispersions — Determination of apparent viscosity using a single cylinder type rotational viscometer method”. International Organization for Standardization, Geneva, Switzerland,www.iso.org. 9. ISO Standard 11357-2, “Plastics — Differential scanning calorimetry (DSC) — Part 2: Determination of glass transition temperature and glass transition step height”. International Organization for Standardization, Geneva, Switzerland,www.iso.org.

Conference: SAMPE NEXUS 2021

Publication Date: 2021/06/29

SKU: TP21-0000000632

Pages: 13

Price: FREE

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