Search

DIGITAL LIBRARY: SAMPE 2022 | CHARLOTTE, NC | MAY 23-26

Get This Paper

Mechanical and Electrical Characterization of 3D Printed Polyamide 6 Nanographene Composite for Electrostatic Discharge Applications

Description

Title: Mechanical and Electrical Characterization of 3D Printed Polyamide 6 Nanographene Composite for Electrostatic Discharge Applications

Authors: Oluwasola K. Arigbabowo, Liam Omer, and Jitendra Tate

DOI: 10.33599/nasampe/s.22.0861

Abstract: Polyamide 6 (PA 6) is an engineering thermoplastic that can be used to develop polymer nanocomposite with high potential in electrostatic discharge applications. By the incorporation of nanofillers in PA 6 to enhance multifunctional properties, PA 6 nanocomposites can serve as technological alternatives to commercial thermoplastics for 3D printing via fused deposition modelling (FDM). Hence, this study evaluated the mechanical and electrical properties of 3D printed PA6 nanographene composites for electrostatic discharge applications. 2, 4 and 6 wt.% of Graphene Nanoplatelets (GNP) was compounded with PA6 using co-rotating twin screw extruder to produce 1.75mm diameter monofilaments for FDM 3D printing. The test samples were printed using commercial-off-the-shelf (COTS) 3D printer, Lulzbot TAZ 6 FDM printer. Morphology, mechanical and electrical characterization was carried out according to their respective ASTM standard. An improvement in tensile and flexural properties were observed with an increase in nanographene addition, and a maximum improvement of 61.4 and 55.9% in tensile and flexural modulus respectively was recorded at 6wt% loading level. Electrical conduction of the insulative polyamide 6 matrix was enhanced by an appreciable reduction of its volume resistivity to 1011 Ω.cm by 2wt% nanographene loading, which seems promising for manufacturing static discharge products.

References: [1] X. Zhang, W. Fan, and T. Liu, ""Fused deposition modeling 3D printing of polyamide-based composites and its applications,"" Composites Communications, vol. 21, p. 100413, 2020/10/01/ 2020, doi: https://doi.org/10.1016/j.coco.2020.100413. [2] A. Dorigato, V. Moretti, S. Dul, S. H. Unterberger, and A. Pegoretti, ""Electrically conductive nanocomposites for fused deposition modelling,"" Synthetic Metals, vol. 226, pp. 7-14, 2017/04/01/ 2017, doi: https://doi.org/10.1016/j.synthmet.2017.01.009. [3] R. Pouyanmehr, M. K. Hassanzadeh-Aghdam, and R. Ansari, ""Effect of graphene nanosheet dispersion on diffusion-induced stresses in layered sn-based nanocomposite electrode for lithium-ion batteries,"" Mechanics of Materials, vol. 145, p. 103390, 2020/06/01/ 2020, doi: https://doi.org/10.1016/j.mechmat.2020.103390. [4] B. Vigolo, C. Coulon, M. Maugey, C. Zakri, and P. Poulin, ""An Experimental Approach to the Percolation of Sticky Nanotubes,"" Science, vol. 309, no. 5736, pp. 920-923, 2005, doi: doi:10.1126/science.1112835. [5] K. Gnanasekaran, G. de With, and H. Friedrich, ""On Packing, Connectivity, and Conductivity in Mesoscale Networks of Polydisperse Multiwalled Carbon Nanotubes,"" The Journal of Physical Chemistry C, vol. 118, no. 51, pp. 29796-29803, 2014/12/26 2014, doi: 10.1021/jp5081669. [6] R. Otten and P. van der Schoot, ""Continuum Percolation of Polydisperse Nanofillers,"" Physical review letters, vol. 103, p. 225704, 11/01 2009, doi: 10.1103/PhysRevLett.103.225704. [7] H. V. Madhad and D. V. Vasava, ""Review on recent progress in synthesis of graphene–polyamide nanocomposites,"" Journal of Thermoplastic Composite Materials, p. 0892705719880942, 2019, doi: 10.1177/0892705719880942. [8] F. Castles et al., ""Microwave dielectric characterisation of 3D-printed BaTiO3/ABS polymer composites,"" Scientific Reports, vol. 6, no. 1, p. 22714, 2016/03/04 2016, doi: 10.1038/srep22714. [9] P. Cataldi, A. Athanassiou, and I. S. Bayer, ""Graphene Nanoplatelets-Based Advanced Materials and Recent Progress in Sustainable Applications,"" Applied Sciences, vol. 8, no. 9, p. 1438, 2018. [Online]. Available: https://www.mdpi.com/2076-3417/8/9/1438. [10] Taulman3D. ""Technical Data Sheet (TDS): Nylon 645."" https://taulman3d.com/nylon-645-spec.html (accessed. [11] ASTM. ""Standard Test Method for Tensile Properties of Plastics."" https://www.astm.org/Standards/D638.htm (accessed. [12] ASTM. ""Standard Test Methods for DC Resistance or Conductance of Insulating Materials."" https://www.astm.org/Standards/D257.htm (accessed. [13] H. V. Madhad, N. S. Mishra, S. B. Patel, S. S. Panchal, R. A. Gandhi, and D. V. Vasava, ""Graphene/graphene nanoplatelets reinforced polyamide nanocomposites: A review,"" High Performance Polymers, vol. 33, no. 9, pp. 981-997, 2021/11/01 2021, doi: 10.1177/09540083211011216. [14] C. J. Jacobs, J. S. Tate, B. Olson, N. Theodoropoulou, and J. H. Koo, ""Thermal characterization of polyamide 11/nanographene platelet nanocomposites,"" (in eng), J Nanosci Nanotechnol, vol. 12, no. 3, pp. 1799-805, Mar 2012, doi: 10.1166/jnn.2012.5158. [15] D. Thomas, ""Developing 3D printable hybrid graphene and carbon fibre polymer nanocomposites for fused filament fabrication,"" Journal of materials research and technology, 2020. [16] D. Thomas, ""WITHDRAWN: Developing 3D printable hybrid graphene and carbon fibre polymer nanocomposites for fused filament fabrication,"" Journal of materials research and technology, 2020. [17] S. Dul, L. Fambri, and A. Pegoretti, ""Fused deposition modelling with ABS–graphene nanocomposites,"" Composites Part A: Applied Science and Manufacturing, vol. 85, pp. 181-191, 2016/06/01/ 2016, doi: https://doi.org/10.1016/j.compositesa.2016.03.013. [18] A. Patel and M. Taufik, ""Nanocomposite materials for fused filament fabrication,"" Materials Today: Proceedings, vol. 47, pp. 5142-5150, 2021/01/01/ 2021, doi: https://doi.org/10.1016/j.matpr.2021.05.438. [19] Y. Yang, M. Zhao, Z. Xia, H. Duan, G. Zhao, and Y. Liu, ""Facile preparation of polyamide 6/exfoliated graphite nanoplate composites via ultrasound-assisted processing,"" Polymer Engineering & Science, vol. 58, no. 10, pp. 1739-1745, 2018, doi: https://doi.org/10.1002/pen.24773. [20] G. G. Tibbetts, I. C. Finegan, and C. Kwag, ""Mechanical and electrical propertiesof vapor-grown carbon fiber thermoplastic composites,"" Molecular Crystals and Liquid Crystals, vol. 387, no. 1, pp. 129-133, 2002/01/01 2002, doi: 10.1080/10587250215229. [21] R. S. Chen, M. F. H. Mohd Ruf, D. Shahdan, and S. Ahmad, ""Enhanced mechanical and thermal properties of electrically conductive TPNR/GNP nanocomposites assisted with ultrasonication,"" PLoS One, vol. 14, no. 9, p. e0222662, 2019, doi: 10.1371/journal.pone.0222662. [22] C.-L. Huang, C.-W. Lou, C.-F. Liu, C.-H. Huang, X.-M. Song, and J.-H. Lin, ""Polypropylene/Graphene and Polypropylene/Carbon Fiber Conductive Composites: Mechanical, Crystallization and Electromagnetic Properties,"" Applied Sciences, vol. 5, no. 4, pp. 1196-1210, 2015. [Online]. Available: https://www.mdpi.com/2076-3417/5/4/1196.

Conference: SAMPE 2022

Publication Date: 2022/05/23

SKU: TP22-0000000861

Pages: 12

Price: $24.00

Get This Paper