Search

DIGITAL LIBRARY: SAMPE 2024 | LONG BEACH, CA | MAY 20-23

Get This Paper

Sustainable, Fire-Resistant Building Materials from Furan-Based Epoxy Resins and Natural Fiber Composites

Description

Title: Sustainable, Fire-Resistant Building Materials from Furan-Based Epoxy Resins and Natural Fiber Composites

Authors: Amy Honnig Bassett, Giuseppe R. Palmese, Ph.D.

DOI: 10.33599/nasampe/s.24.0132

Abstract: "With increased greenhouse gas emissions, some anticipate a 50 % increase in extreme wildfires (burning > 25,000 acres) by 2100 [1]. The threat of wildfire damage requires the development of fire-resistant and more sustainable building materials. Polymer/fiber reinforced composites have the potential to be used if appropriate starting materials are chosen. Therefore, there is a need to develop new materials for composites that are both fire resistant and renewably sourced. In this study, sustainable, fire-resistant polymer/fiber reinforced composites were fabricated. A furan-based epoxy resin was used as the polymer matrix. Furan is obtained from polysaccharides found in biomass wastes and is known to increase the char yield of thermosets made with them. Flax fibers were used as the fiber reinforcements. The thermal stabilities of the epoxy resin and fibers were evaluated separately using Thermogravimetric Analysis (TGA). Composites were fabricated using Resin Transfer Molding (RTM). The fire performance of this system was evaluated using UL standards and compared to glass fiber reinforced composites. "

References: 1.Fisher, L.; Ziaja, S., "California's Fourth Climate Change Assessment: Statewide Summary Report". (2018). 2.Bellucci, F.; Camino, G., Flammability of Polymer Composites. In Wiley Encyclopedia of Composites, Nicolais, L., Ed. John Wiley & Sons, Inc.: 2012. 3.Galaska, M. L.; Horrocks, A. R.; Morgan, A. B., ""Flammability of Natural Plant and Animal Fibers: A Heat Release Survey"". Fire and Materials (2016). 4.Saba, N.; Jawaid, M.; Paridah, M. T.; Al-othman, O. Y., ""A Review on Flammability of Epoxy Polymer, Cellulosic and Non-Cellulosic Fiber Reinforced Epoxy Composites"". Polym. Adv. Technol. 27 (2016): 577-590. 5.Rakotomalala, M.; Wagner, S.; Döring, M., ""Recent Developments in Halogen Free Flame Retardants for Epoxy Resins for Electrical and Electronic Applications"". Materials 3 (2010): 4300-4327. 6.Rad, E. R.; Vahabi, H.; de Anda, A. R.; Saeb, M. R.; Thomas, S., ""Bio-epoxy Resins with Inherent Flame Retardancy"". Progress in Organic Coatings 135 (2019): 608-612. 7.Witkowski, A.; Stec, A. A.; Hull, T. R., Thermal Decomposition of Polymeric Materials. In SFPE Handbook of Fire Protection Engineering, Fifth ed.; Hurley, M. J., Ed. Springer: New York, 2016. 8.Zhi, M.; Yang, X.; Fan, R.; Yue, S.; Zheng, L.; Liu, Q.; He, Y., ""A Comprehensive Review of Reactive Flame-Retardant Epoxy Resin: Fundamentals, Recent Developments, and Perspectives"". Polymer Degradation and Stability 201 (2022): 109976. 9.Morgan, A. B., ""The Future of Flame Retardant Polymers- Unmet Needs and Likely New Approaches"". Polymer Reviews (2018). 10.Dunlop, A. P.; Peters, F. N., The Furans. Reinhouse Publishing Corporation, 1953; Vol. 119. 11.Hu, F.; Yadav, S. K.; La Scala, J. J.; Sadler, J. M.; Palmese, G. R., ""Preparation and Characterization of Fully Furan-Based Renewable Thermosetting Epoxy-Amine Systems"". Macromol. Chem. Phys. 216 (2015): 1441-1446. 12.Gandini, A.; Lacerda, T. M.; Caravlho, A. J. F.; Trovatti, E., ""Progress of Polymers from Renewable Resources: Furans, Vegetable Oils, and Polysaccharides"". Chem. Rev. 116 (2016): 1637-1669. 13.SFPE Handbook of Fire Protection Engineering. Fifth ed.; Hurley, M. J., Ed. Springer: 2016. 14.ASTM D3801-20a, ""Standard Test Method for Measuring the Comparative Burning Characteristics of Solid Plastics in a Vertical Position"" ASTM International: West Conshohocken, PA, 2020. 15.Fitzer, E.; Schäfer, W., ""The Effect of Crosslinking on the Formation of Glasslike Carbons from Thermosetting Resins"". Carbon 8 (1970): 353-364. 16.Fitzer, E.; Schaefer, W.; Yamada, S., ""The Formation of Glasslike Carbon by Pyrolysis of Polyfurfuryl Alcohol and Phenolic Resin"". Carbon 7 (1969): 643-648. 17.Savage, G., Carbon-Carbon Composites. First ed.; New York: Chapman & Hall, 1993. 18.Mouritz, A. P.; Gibson, A. G., Fire Properties of Polymer Composite Materials. Netherlands: Springer, 2006; Vol. 143.

Conference: SAMPE 2024

Publication Date: 2024/05/20

SKU: TP24-0000000132

Pages: 8

Price: $16.00

Get This Paper