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DIGITAL LIBRARY: SAMPE 2025 | INDIANAPOLIS, IN | MAY 19-22

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Enhancing Thermal and Mechanical Properties of Countertop Epoxy Through ZrO2 Nanoparticle Reinforcement

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Title: Enhancing Thermal and Mechanical Properties of Countertop Epoxy Through ZrO2 Nanoparticle Reinforcement

Authors: Fariha B. Rahman, Hassan Mahfuz, Masashi Kurashina

DOI: 10.33599/nasampe/s.25.0233

Abstract: Countertop epoxy is well-regarded for its durability, heat resistance, and seamless finish, making it a favored choice in kitchens, bars, and commercial environments. Its brittleness and limited thermal stability may restrict its use in more demanding environments. This research examines the possible improvement of the performance by incorporating ZrO₂ nanoparticles. Due to their thermal stability and fracture toughness, ZrO₂ nanoparticles have the potential to greatly enhance the properties of epoxy materials. Comprehensive analyses, including Differential Scanning Calorimetry (DSC), tensile, flexural, and impact testing, reveal significant benefits from incorporating ZrO₂. Notably, it has been observed that 2 % ZrO₂ reinforcement boosts the glass transition temperature (Tg) by 25 %, increasing it from 56 °C to 70 °C, indicating enhanced thermal stability. The best mechanical performance occurs with a 1 % ZrO₂ concentration, resulting in a 70 % improvement in flexural modulus and considerable gains in tensile strength and impact energy absorption. When compared to other nanoparticles like boron nitride and Mg₂Al(OH)₆(DBS)ₙH₂O, ZrO₂ demonstrates superior performance in terms of glass transition temperature (Tg), flexural strength, and modulus. This makes ZrO₂-reinforced epoxy an excellent choice for industrial applications, offering a combination of durability, high performance, and aesthetic appeal.

References: [1] S. S. Yao, F. L. Jin, K. Y. Rhee, D. Hui and S. J. and Parkd, "Recent Advances in CarbonFiber-Reinforced Thermoplastic Composites: A Review," Composites Part B, pp. 241-250, 2018. [2] R. Garvey, "Potential for Advanced Thermoplastic Composites in Space Systems," Oak Ridge National Laboratory, Oak Ridge, 1990. [3] A. Pegoretti, "Recycling Concepts for Short-Fiber-Reinforced and Particle-Filled Thermoplastic Composites: A Review," Advanced Industrial and Engineering Polymer Research, pp. 93-104, 2021. [4] M. Hou, L. Ye and Y. W. Mai, "Manufacturing Process and Mechanical Properties of Thermoplastic Composite Components," Journal of Materials Processing Technology, pp. 334-338, 1997. [5] N. M. DeNardo, "ADDITIVE MANUFACTURING OF CARBON FIBER-REINFORCED THERMOPLASTIC COMPOSITES," Purdue University, West Lafayette, 2016. [6] K. M. M. Billah, F. A. R. Lorenzana, N. L. Martinez, S. Chacon and R. B. and Wicker, "Thermal Analysis of Thermoplastic Materials Filled with Chopped Fiber for Large Area 3D Printing," in Solid Freeform Fabrication 2019: Proceedings of the 30th Annual International Solid Freeform Fabrication Symposium – An Additive Manufacturing Conference, Austin, 2019. [7] H. M. Technologies, "7 Families of Additive Manufacturing Quick Reference Guide," [Online]. Available: www.hybridmanutech.com. [8] D. Zindani and K. and Kumar, "An Insight into Additive Manufacturing of Fiber Reinforced Polymer Composite," International Journal of Lightweight Materials and Manufacture, vol. 46, pp. 267-278, 2019. [9] M. Vincent, T. Giroud, A. Clarke and C. and Eberhardt, "Description and Modeling of Fiber Orientation in Injection Molding of Fiber Reinforced Thermoplastics," Polymer, no. 46, pp. 6719-6725, 2005. [10] C. Duty and a. e. al., "Structure and mechanical behavior of big area additive manufacturing (BAAM) materials," Rapid Prototyping Journal, vol. 23, no. 1, p. 181–189, 2017. [11] J. M. Chacón, M. A. Caminero, E. García-Plaza and P. J. and Núñez, "Additive manufacturing of PLA structures using fused deposition modelling: Effect of process parameters on mechanical properties and their optimal selection," Material Design, vol. 124, p. 143–157, 2017. doi: 10.1016/j.matdes.2017.03.065. [12] B. Brenken, E. Barocio, A. Favaloro, V. Kunc and R. and Pipes, "Fused filament fabrication of fiber-reinforced polymers: A review," Additive Manufacturing, p. 21:11–16, 2018. [13] A. Pricci and G. and Percoco, "A generalized method aiming at predicting the polymer melt fow feld in the metering zone of large-scale single-screw extruders," The International Journal of Advanced Manufacturing Technology, vol. 132, pp. 227-290, 2024. https://doi.org/10.1007/s00170-024-13346-9. [14] A. A. Hassen, J. Lindahl, X. Chen, B. Post, L. Love and V. and Kunc, "ADDITIVE MANUFACTURING OF COMPOSITE TOOLING USING HIGH TEMPERATURE THERMOPLASTIC MATERIALS," in SAMPE Conference Proceedings, Long Beach, 2016. [15] P. Burgos Pintos and e. al., "Influence of the carbon fiber length distribution in polymer matrix composites for large format additive manufacturing via fused granular fabrication," Polymers, vol. 16, no. 1, p. 60, 2023. https://doi.org/10.3390/polym16010060. [16] A. Rhodes and e. al., "Analysis of Fiber Attrition and Mechanical Performance in LargeFormat Additive Manufacturing of Long-Fiber Reinforced Polymer Composites," in International Solid Freeform Fabrication Symposium, 2022. https://doi.org/http://dx.doi.org/10.26153/tsw/44146. [17] P. Zhuo and e. al., "Material extrusion additive manufacturing of continuous fibre reinforced polymer matrix composites: A review and outlook," Composites Part B: Engineering, vol. 224, p. 109143, 2021. https://doi.org/10.1016/j.compositesb.2021.109143. [18] G. Goh, V. Dikshit, A. Nagalingam, G. Goh, S. Agarwala, S. Sing, J. Wei and W. and Yeong, "Characterization of Mechanical Properties and Fracture Mode of Additively Manufactured Carbon Fiber and Glass Fiber Reinforced Thermoplastics," Materials and Design, vol. 137, pp. 79-89, 2018. [19] U. S. C. E. a. T. S. D. A. M. Office and V. Kunc, "Vinylester and Polyester 3D Printing, ORNL/TM-2019/1404 CRADA/NFE-17-06792," LABORATORY, Oak Ridge, 2019. OAK RIDGE NATIONAL [20] V. Kumar, S. P. Alwekar, V. Kunc, E. Cakmak, V. Kishore, T. Smith, J. Lindahl, U. Vaidya, C. Blue, M. Theodore, S. Kim and A. A. and Hassen, "High-Performance Molded Composites using Additively Manufactured Preforms with Controlled Fiber and Pore Morphology," Additive Manufacturing, vol. 37, no. 101733, 2021. [21] V. Kumar, C. Nielson, P. Yeole, R. Spencer, A. Kircaliali, C. Cramer, A. S. Badesha, D. Nuttall, U. Vaidya and V. and Kunc, "Large-scale continuous carbon/glass fiber additivecompression," in CAMX – The Composites and Advanced Materials Expo Conference Proceedings, Dallas, 2021. [22] E. Barocio and e. al., "Compression molding of hybrid continuous and discontinuous fiber reinforced thermoplastics for enhancing strength characteristics," SAMPE Journal, vol. 59, no. 5, 2023. https://doi.org/10.33599/sj.v59no5.03. [23] J. Brackett and e. al., "Continuous fiber 3D printing for compression overmolding," in CAMX – The Composites and Advanced Materials Expo Conference Proceedings, Atlanta, 2023. https://doi.org/10.33599/nasampe/c.23.0197. [24] E. Piatt and e. al., "Design of lightweight, high stiffness, and low strength parts using metallic skins for large format additive manufacturing processes," Journal of Advanced Materials, no. January, 2024. https://doi.org/10.33599/nasampe/c.23.0025.

Conference: SAMPE 2025

Publication Date: 2025/05/19

SKU: TP25-0000000233

Pages: 15

Price: $30.00

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