Title: Influence of Surface Treatment on the Interfacial and Mechanical Performance of Metal-Insert Overmolded Composites
Authors: Subhabrata Saha, Segun Isaac Talabi, Nadim Hmeidat, Ryan Ogle, Brittany Rodriguez, David Nuttall, Jesse Murphy, Marco Martinez, Vipin Kumar, Ahmed Hassen
DOI:
Abstract: Structural composites with metal inserts are gaining increasing interest enabling light weight design for energy efficiency, provide insulation, corrosion protection without compromising mechanical integrity. Such over molded metal-polymer composites show strong potential in many automotive and aerospace component parts, e.g., car bumper, chassis, door, brackets, fasteners, etc. Despite several advantages, metal-polymer dissimilar interface remains a weak spot in structural design, requiring further investigation to improve interfacial interlocking. The current work focuses on enhancing the metal-polymer adhesion between stainless steel inserts and polymer matrices (e.g. acrylonitrile butadiene styrene resin (ABS), and polyamide 66 (PA66)) through surface treatment via chemical etching and mechanical roughening. In the chemical etching process, metal substrates were treated with aqua regia solution for different time intervals to evaluate surface roughness measured by water contact angle and morphology analysis. For mechanical roughening approach, metal inserts were subjected to blasting for surface abrasion. Treated samples were also functionalized with aminosilane coupling agent which showed successful grafting on the surface measured by water contact angle. Metal inserts with micro level surface roughness through etching exhibited significant 26% improvement in adhesion strength compared to untreated inserts for ABS; whereas, the effect of silane treatment on the interfacial strength was found to be more effective for PA66.
References: 1] Aliyeva N, Sas HS, Saner Okan B. Recent developments on the overmolding process for the fabrication of thermoset and thermoplastic composites by the integration of nano/micron-scale reinforcements. Composites Part A: Applied Science and Manufacturing. 2021;149:106525. [2] Kim KJ, Rhee MH, Choi B-I, Kim C-W, Sung C-W, Han C-P, et al. Development of application technique of aluminum sandwich sheets for automotive hood. International Journal of Precision Engineering and Manufacturing. 2009;10(4):71–5. [3] Pokkalla DK, Garg N, Paramanathan M, Kumar V, Rencheck ML, Nandwana P, et al. Design optimization of lightweight automotive seatback through additive manufacturing compression overmolding of metal polymer composites. Composite Structures. 2024;349-350:118504. [4] Carradò A, Ravindra NM. Metal/Polymer/Metal Sandwich Systems: An Overview. JOM. 2023;75(12):5126–40. [5] Vasconcelos RL, Oliveira GHM, Amancio-Filho ST, Canto LB. Injection overmolding of polymer-metal hybrid structures: A review. Polymer Engineering & Science. 2023;63(3):691722. [6] Schuberth A, Göring M, Lindner T, Töberling G, Puschmann M, Riedel F, et al. Effect of new adhesion promoter and mechanical interlocking on bonding strength in metal-polymer composites. IOP Conference Series: Materials Science and Engineering. 2016;118(1):012041. [7] Novák L, Fojtl L, Kadlečková M, Maňas L, Smolková I, Musilová L, et al. Surface Modification of Metallic Inserts for Enhancing Adhesion at the Metal–Polymer Interface. Polymers. 2021;13(22):4015. [8] Zhang Y, Zhang Z, Yang J, Yue Y, Zhang H. Fabrication of superhydrophobic surface on stainless steel by two-step chemical etching. Chemical Physics Letters. 2022;797:139567. [9] Wei F, Wei Y, Yao X, Li X, Wei Z, Zhang S, et al. Review: Enhancing bond strength of heterogeneous metal-polymer components the perspective of surface micro-nano morphology construction. Journal of Materials Science. 2025;60(14):6023–58. [10] Lee H, Song S-I, Jang K-S. The Role of Surface Treatment and Coupling Agents for Adhesion between Stainless Steel (SUS) and Polyamide (PA) of Heterojunction Bilayer Composites. Polymers. 2024;16(7):896. [11] Grujicic M. Injection Overmolding of Polymer–Metal Hybrid Structures. Joining of Polymer‐Metal Hybrid Structures2018. p. 277–305. [12] Jussila P, Ali-Löytty H, Lahtonen K, Hirsimäki M, Valden M. Effect of surface hydroxyl concentration on the bonding and morphology of aminopropylsilane thin films on austenitic stainless steel. Surface and Interface Analysis. 2010;42(3):157–64. 16 [13] Seo OB, Saha S, Kim NH, Lee JH. Preparation of functionalized MXene-stitched-graphene oxide/poly (ethylene-co-acrylic acid) nanocomposite with enhanced hydrogen gas barrier properties. Journal of Membrane Science. 2021;640:119839. [14] Chen L, Xiao Z, Chan PCH, Lee Y-K, Li Z. A comparative study of droplet impact dynamics on a dual-scaled superhydrophobic surface and lotus leaf. Applied Surface Science. 2011;257(21):8857–63. [15] Zhang H, Han J, Sun Y, Huang Y, Zhou M. MC3T3-E1 cell response to stainless steel 316L with different surface treatments. Materials Science and Engineering: C. 2015;56:22–9. [16] Saha S, Son W, Kim NH, Lee JH. Fabrication of impermeable dense architecture containing covalently stitched graphene oxide/boron nitride hybrid nanofiller reinforced semiinterpenetrating network for hydrogen gas barrier applications. Journal of Materials Chemistry A. 2022;10(8):4376–91. [17] Howarter JA, Youngblood JP. Surface Modification of Polymers with 3Aminopropyltriethoxysilane as a General Pretreatment for Controlled Wettability. Macromolecules. 2007;40(4):1128–32. [18] Westra KL, Thomson DJ. Effect of tip shape on surface roughness measurements from atomic force microscopy images of thin films. Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures Processing, Measurement, and Phenomena. 1995;13(2):344–9.
Conference: SAMPE 2026
Publication Date: 2026/04/27
SKU: 121
Pages: 17
Price: $34.00
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